Add playing a super spy to the long list of accomplishments Olivia Munn has outside of her television hosting duties on G4’s Attack of the Show. Munn will guest star in NBC’s Chuck premiere episode along with baddie Dolph Lundgren. Munn’s role will be an “impossibly cool, smart, and pretty CIA agent who intimidates and schools Chuck and Morgan”.

The host/actress/geek goddess also has a regular role on the upcoming NBC midseason comedy Perfect Couples as well as guest spots on Comedy Central’s The Daily Show.

In related casting news for Chuck, the show is casting a “real-life supermodel to play a dangerous, sexy, and kick-ass supermodel in this season’s second episode, titled “Chuck vs. the Suitcase.”

Chuck premieres its fourth season on NBC on September 20, 2010.

[Source] EW